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Scalability and stability of very thin, roll-to-roll processed, large area, indium-tin-oxide free polymer solar cell modules

Identifieur interne : 000576 ( Main/Repository ); précédent : 000575; suivant : 000577

Scalability and stability of very thin, roll-to-roll processed, large area, indium-tin-oxide free polymer solar cell modules

Auteurs : RBID : Pascal:13-0143292

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English descriptors

Abstract

Polymer solar cell modules were prepared directly on thin flexible barrier polyethylene terephthalate foil. The performance of the modules was found to be scalable from a single cell with an area of 6 cm2 to modules with a total area of up to 186 cm2. The substrate thickness was also explored and the performance was found to be independent of thickness in the range of 20-130 μm. The thinner substrates were found to present some challenge regarding handling but were not limited in performance. Large area modules on a substrate thickness of 45 μm were finally prepared by full roll-to-roll processing employing P3HT:PCBM as the active material and were found to exhibit a total area efficiency of >1% (1000 W/m-2; AM1.5G) with a typical active-area efficiency in the 1.5-1.6% for total module area of >110 cm2 due to high fill factors in excess of 50%. The modules were also found to have an active-area efficiency of >1% under low light levels (∼100 W m-2). The modules were then subjected to extensive stability testing for a minimum of 1000 h employing several ISOS protocols. The modules presented higher than 80% of the initial performance (T80) in the dark (ISOS-D-1), in dark under elevated temperature of 65 °C (ISOS-D-2), under low light (ISOS-LL), under full sunlight (ISOS-L-2), and under outdoor testing (ISOS-O), which was conducted in two locations in India and Denmark. We estimate maximum T80 for those tests to be 2800, 5000, 1300, 1000, and 3500 h respectively. The modules showed significant sensitivity to high humidity and had low values for T80 for dark storage tests at 50 °C/85%RH (ISOS-D-3) and accelerated operation conditions with 0.7 sun/65 oC/50%RH (ISOS-L-3). We found the modules to be particularly suited for information and communications technology (ICT) and mobile applications where low humidity (<50%) and lower temperatures (<65 °C) can be anticipated and we estimate operational lifetimes in excess of 1 year.

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Pascal:13-0143292

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<term>Doped materials</term>
<term>Durability</term>
<term>Ester</term>
<term>Ethylene terephthalate polymer</term>
<term>Fill factor</term>
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<term>Humidity</term>
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<div type="abstract" xml:lang="en">Polymer solar cell modules were prepared directly on thin flexible barrier polyethylene terephthalate foil. The performance of the modules was found to be scalable from a single cell with an area of 6 cm
<sup>2</sup>
to modules with a total area of up to 186 cm
<sup>2</sup>
. The substrate thickness was also explored and the performance was found to be independent of thickness in the range of 20-130 μm. The thinner substrates were found to present some challenge regarding handling but were not limited in performance. Large area modules on a substrate thickness of 45 μm were finally prepared by full roll-to-roll processing employing P3HT:PCBM as the active material and were found to exhibit a total area efficiency of >1% (1000 W/m
<sup>-2</sup>
; AM1.5G) with a typical active-area efficiency in the 1.5-1.6% for total module area of >110 cm
<sup>2</sup>
due to high fill factors in excess of 50%. The modules were also found to have an active-area efficiency of >1% under low light levels (∼100 W m
<sup>-2</sup>
). The modules were then subjected to extensive stability testing for a minimum of 1000 h employing several ISOS protocols. The modules presented higher than 80% of the initial performance (T80) in the dark (ISOS-D-1), in dark under elevated temperature of 65 °C (ISOS-D-2), under low light (ISOS-LL), under full sunlight (ISOS-L-2), and under outdoor testing (ISOS-O), which was conducted in two locations in India and Denmark. We estimate maximum T80 for those tests to be 2800, 5000, 1300, 1000, and 3500 h respectively. The modules showed significant sensitivity to high humidity and had low values for T80 for dark storage tests at 50 °C/85%RH (ISOS-D-3) and accelerated operation conditions with 0.7 sun/65 oC/50%RH (ISOS-L-3). We found the modules to be particularly suited for information and communications technology (ICT) and mobile applications where low humidity (<50%) and lower temperatures (<65 °C) can be anticipated and we estimate operational lifetimes in excess of 1 year.</div>
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<sup>2</sup>
to modules with a total area of up to 186 cm
<sup>2</sup>
. The substrate thickness was also explored and the performance was found to be independent of thickness in the range of 20-130 μm. The thinner substrates were found to present some challenge regarding handling but were not limited in performance. Large area modules on a substrate thickness of 45 μm were finally prepared by full roll-to-roll processing employing P3HT:PCBM as the active material and were found to exhibit a total area efficiency of >1% (1000 W/m
<sup>-2</sup>
; AM1.5G) with a typical active-area efficiency in the 1.5-1.6% for total module area of >110 cm
<sup>2</sup>
due to high fill factors in excess of 50%. The modules were also found to have an active-area efficiency of >1% under low light levels (∼100 W m
<sup>-2</sup>
). The modules were then subjected to extensive stability testing for a minimum of 1000 h employing several ISOS protocols. The modules presented higher than 80% of the initial performance (T80) in the dark (ISOS-D-1), in dark under elevated temperature of 65 °C (ISOS-D-2), under low light (ISOS-LL), under full sunlight (ISOS-L-2), and under outdoor testing (ISOS-O), which was conducted in two locations in India and Denmark. We estimate maximum T80 for those tests to be 2800, 5000, 1300, 1000, and 3500 h respectively. The modules showed significant sensitivity to high humidity and had low values for T80 for dark storage tests at 50 °C/85%RH (ISOS-D-3) and accelerated operation conditions with 0.7 sun/65 oC/50%RH (ISOS-L-3). We found the modules to be particularly suited for information and communications technology (ICT) and mobile applications where low humidity (<50%) and lower temperatures (<65 °C) can be anticipated and we estimate operational lifetimes in excess of 1 year.</s0>
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</fC03>
<fC03 i1="12" i2="X" l="FRE">
<s0>Haute température</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG">
<s0>High temperature</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA">
<s0>Alta temperatura</s0>
<s5>12</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE">
<s0>Rayonnement solaire</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG">
<s0>Solar radiation</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA">
<s0>Radiación solar</s0>
<s5>13</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE">
<s0>Etude en condition extérieure</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG">
<s0>Outdoor study</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA">
<s0>Estudio en condición exterior</s0>
<s5>14</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE">
<s0>Inde</s0>
<s2>NG</s2>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="X" l="ENG">
<s0>India</s0>
<s2>NG</s2>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="X" l="SPA">
<s0>India</s0>
<s2>NG</s2>
<s5>15</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE">
<s0>Danemark</s0>
<s2>NG</s2>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="X" l="ENG">
<s0>Denmark</s0>
<s2>NG</s2>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="X" l="SPA">
<s0>Dinamarca</s0>
<s2>NG</s2>
<s5>16</s5>
</fC03>
<fC03 i1="17" i2="X" l="FRE">
<s0>Humidité</s0>
<s5>17</s5>
</fC03>
<fC03 i1="17" i2="X" l="ENG">
<s0>Humidity</s0>
<s5>17</s5>
</fC03>
<fC03 i1="17" i2="X" l="SPA">
<s0>Humedad</s0>
<s5>17</s5>
</fC03>
<fC03 i1="18" i2="X" l="FRE">
<s0>Technologie information</s0>
<s5>18</s5>
</fC03>
<fC03 i1="18" i2="X" l="ENG">
<s0>Information technology</s0>
<s5>18</s5>
</fC03>
<fC03 i1="18" i2="X" l="SPA">
<s0>Tecnología información</s0>
<s5>18</s5>
</fC03>
<fC03 i1="19" i2="X" l="FRE">
<s0>Technologie communication</s0>
<s5>19</s5>
</fC03>
<fC03 i1="19" i2="X" l="ENG">
<s0>Communication technology</s0>
<s5>19</s5>
</fC03>
<fC03 i1="19" i2="X" l="SPA">
<s0>Tecnología comunicacíon</s0>
<s5>19</s5>
</fC03>
<fC03 i1="20" i2="X" l="FRE">
<s0>Durée vie</s0>
<s5>20</s5>
</fC03>
<fC03 i1="20" i2="X" l="ENG">
<s0>Lifetime</s0>
<s5>20</s5>
</fC03>
<fC03 i1="20" i2="X" l="SPA">
<s0>Tiempo vida</s0>
<s5>20</s5>
</fC03>
<fC03 i1="21" i2="X" l="FRE">
<s0>Durabilité</s0>
<s5>21</s5>
</fC03>
<fC03 i1="21" i2="X" l="ENG">
<s0>Durability</s0>
<s5>21</s5>
</fC03>
<fC03 i1="21" i2="X" l="SPA">
<s0>Durabilidad</s0>
<s5>21</s5>
</fC03>
<fC03 i1="22" i2="X" l="FRE">
<s0>Oxyde d'indium</s0>
<s5>22</s5>
</fC03>
<fC03 i1="22" i2="X" l="ENG">
<s0>Indium oxide</s0>
<s5>22</s5>
</fC03>
<fC03 i1="22" i2="X" l="SPA">
<s0>Indio óxido</s0>
<s5>22</s5>
</fC03>
<fC03 i1="23" i2="X" l="FRE">
<s0>Ethylène téréphtalate polymère</s0>
<s2>NK</s2>
<s5>23</s5>
</fC03>
<fC03 i1="23" i2="X" l="ENG">
<s0>Ethylene terephthalate polymer</s0>
<s2>NK</s2>
<s5>23</s5>
</fC03>
<fC03 i1="23" i2="X" l="SPA">
<s0>Etileno tereftalato polímero</s0>
<s2>NK</s2>
<s5>23</s5>
</fC03>
<fC03 i1="24" i2="X" l="FRE">
<s0>Thiophène dérivé polymère</s0>
<s2>NK</s2>
<s5>24</s5>
</fC03>
<fC03 i1="24" i2="X" l="ENG">
<s0>Thiophene derivative polymer</s0>
<s2>NK</s2>
<s5>24</s5>
</fC03>
<fC03 i1="24" i2="X" l="SPA">
<s0>Tiofeno derivado polímero</s0>
<s2>NK</s2>
<s5>24</s5>
</fC03>
<fC03 i1="25" i2="X" l="FRE">
<s0>Acide butyrique</s0>
<s2>NK</s2>
<s5>25</s5>
</fC03>
<fC03 i1="25" i2="X" l="ENG">
<s0>Butyric acid</s0>
<s2>NK</s2>
<s5>25</s5>
</fC03>
<fC03 i1="25" i2="X" l="SPA">
<s0>Butírico ácido</s0>
<s2>NK</s2>
<s5>25</s5>
</fC03>
<fC03 i1="26" i2="X" l="FRE">
<s0>Ester</s0>
<s5>26</s5>
</fC03>
<fC03 i1="26" i2="X" l="ENG">
<s0>Ester</s0>
<s5>26</s5>
</fC03>
<fC03 i1="26" i2="X" l="SPA">
<s0>Ester</s0>
<s5>26</s5>
</fC03>
<fC03 i1="27" i2="3" l="FRE">
<s0>Composé du fullerène</s0>
<s5>27</s5>
</fC03>
<fC03 i1="27" i2="3" l="ENG">
<s0>Fullerene compounds</s0>
<s5>27</s5>
</fC03>
<fC03 i1="28" i2="3" l="FRE">
<s0>Matériau dopé</s0>
<s5>46</s5>
</fC03>
<fC03 i1="28" i2="3" l="ENG">
<s0>Doped materials</s0>
<s5>46</s5>
</fC03>
<fC03 i1="29" i2="X" l="FRE">
<s0>Fiabilité</s0>
<s5>47</s5>
</fC03>
<fC03 i1="29" i2="X" l="ENG">
<s0>Reliability</s0>
<s5>47</s5>
</fC03>
<fC03 i1="29" i2="X" l="SPA">
<s0>Fiabilidad</s0>
<s5>47</s5>
</fC03>
<fC03 i1="30" i2="X" l="FRE">
<s0>8105T</s0>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="31" i2="X" l="FRE">
<s0>ITO</s0>
<s4>INC</s4>
<s5>82</s5>
</fC03>
<fC03 i1="32" i2="X" l="FRE">
<s0>Procédé roll-to-roll</s0>
<s4>CD</s4>
<s5>96</s5>
</fC03>
<fC03 i1="32" i2="X" l="ENG">
<s0>Roll-to-roll process</s0>
<s4>CD</s4>
<s5>96</s5>
</fC03>
<fC03 i1="33" i2="X" l="FRE">
<s0>ICTS</s0>
<s4>CD</s4>
<s5>97</s5>
</fC03>
<fC03 i1="33" i2="X" l="ENG">
<s0>ICTS</s0>
<s4>CD</s4>
<s5>97</s5>
</fC03>
<fC07 i1="01" i2="X" l="FRE">
<s0>Asie</s0>
<s2>NG</s2>
</fC07>
<fC07 i1="01" i2="X" l="ENG">
<s0>Asia</s0>
<s2>NG</s2>
</fC07>
<fC07 i1="01" i2="X" l="SPA">
<s0>Asia</s0>
<s2>NG</s2>
</fC07>
<fC07 i1="02" i2="X" l="FRE">
<s0>Europe</s0>
<s2>NG</s2>
</fC07>
<fC07 i1="02" i2="X" l="ENG">
<s0>Europe</s0>
<s2>NG</s2>
</fC07>
<fC07 i1="02" i2="X" l="SPA">
<s0>Europa</s0>
<s2>NG</s2>
</fC07>
<fN21>
<s1>119</s1>
</fN21>
<fN44 i1="01">
<s1>OTO</s1>
</fN44>
<fN82>
<s1>OTO</s1>
</fN82>
</pA>
</standard>
</inist>
</record>

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